STARTEX CHEMICAL INC -- LACQUER THINNER -- 8010-00N051307
===================== Product Identification ===================== Product ID:LACQUER THINNER MSDS Date:09/27/1991 FSC:8010 NIIN:00N051307 === Responsible Party === Company Name:STARTEX CHEMICAL INC Box:687 City:CONROE State:TX ZIP:77305 Country:US Info Phone Num:409-539-6244 Emergency Phone Num:800-424-9300(CHEMTREC) CAGE:OYFV5 === Contractor Identification === Company Name:STARTEX CHEMICAL INC Address:5 HACKBERRY LANE Box:3087 City:CONROE State:TX ZIP:77305 Country:US Phone:800-424-9300(CHEMTREC)/936-539-6244 CAGE:OYFV5 ============= Composition/Information on Ingredients ============= Ingred Name:VM&P NAPHTHA; (ALIPHATIC PETROLEUM DISTILLATES) (CONTAINING INGS 2 & 3) CAS:64742-89-8 Fraction by Wt: 20-25% OSHA PEL:300 PPM;400 STEL ACGIH TLV:300 PPM Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 7% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CYCLOHEXANE (SARA III) CAS:110-82-7 RTECS #:GU6300000 Fraction by Wt: 3.5% OSHA PEL:300 PPM ACGIH TLV:300 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 40-45% OSHA PEL:200 PPM ACGIH TLV:50 PPM, S EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 18-23% OSHA PEL:200 PPM ACGIH TLV:200 PPM;300 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHANOL; (METHYL ALCOHOL) (SARA III) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: <4% OSHA PEL:200 PPM, S ACGIH TLV:200 PPM;250 STEL, S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHANOL, 2-BUTOXY-; (ETHYLENE GLYCOL MONOBUTYL ETHER) (SARA III) CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 2-4% OSHA PEL:50 PPM, S ACGIH TLV:25 PPM, S Ingred Name:EFTS OF OVEREXP:KETONE/N-HEXANE. ING 7 CAUSES HARM TO FETUS IN LAB ANIMAL STUDIES. HARM TO FETUS OCCURS ONLY AT (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:EXPOS LEVELS THAT HARM PREGNANT ANIMAL. OVEREXP TO THIS MATL/ITS COMPONENTS HAS APPARENTLY BEEN FOUND TO (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:CAUSE FOLLOWING EFTS IN LAB ANIMALS:LIVER/BLOOD ABNORMS, KIDNEY, LUNGS, SPLEEN, BRAIN, NERV SYS/TESTIS (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:DMG & HAS BEEN SUGGESTED AS CAUSE OF FOLLOWING EFTS IN HUMANS:LIVER ABNORMS, EYE DMG. NOTE:TOLUENE (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:APPEARS ON NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . ANIMAL STUDIES CLEARLY DEMONSTRATED (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:DOSE-RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC TISS, BLOOD, KIDNEYS & LIVER, ASSOC W/ADMIN OF ETHYLENE (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:GLYCOL MONOBUTYL ETHER (EGBE). (EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO.90-118 . RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:TO FORMALDEHYDE & FORMIC ACID. THESE METABOLITES MAY CAUSE METABOLIC ACIDOSIS, VISUAL DISTURBS & (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:BLINDNESS. SINCE METABOLISM IS REQD FOR THESE TOX SYMPS, THEIR ONSET MAY BE DELAYED FROM 6-30 HRS (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:FOLLOWING INGEST. ETHANOL COMPETES FOR SAME METABOLIC PATHWAY & HAS BEEN USED AS ANTIDOTE. METHANOL IS (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:EFTIVELY REMOVED BY HEMODIALYSIS. INHAL:REMOVE INDIVIDUAL TO FRESH AIR. IF BRTHG IS DFCLT, ADMIN OXYGEN. (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19:IF BREATHING HAS STOPPED GIVE ARTF RESP. KEEP PERSON WARM, QUIET & GET MEDICAL ATTENTION. RTECS #:9999999ZZ Ingred Name:SPILL PROC:COMPLETED. STOP SPILL AT SOURCE, DIKE AREA OF SPILL TO PVNT SPREADING, PUMP LIQ TO SALVAGE TANK. (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21:REMAINING LIQ MAY BE TAKEN UP ON SAND, CLAY, EARTH, FLOOR ABSORB/OTHER ABSORB MATL & SHOVELED INTO (ING 23) RTECS #:9999999ZZ Ingred Name:ING 22:CNTNRS. PVNT RUN-OFF TO SEWERS, STREAMS/OTHER BODIES OF WATER. IF RUN-OFF OCCURS, NOTIFY PROPER AUTHS AS (ING 24) RTECS #:9999999ZZ Ingred Name:ING 23:REQUIRED, THAT A SPILL HAS OCCURED. RTECS #:9999999ZZ Ingred Name:RESP PROT:CNDTNS (SEE YOUR SAFETY SUPPLIER). ENGINEERING/ADMIN CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:EYES:CAN CAUSE SEV IRRIT, REDNESS, TEARING, BLURRED VISION. SKIN:PRLNG/RPTD CONT CAN CAUSE MOD IRRIT, DEFAT, DERM. INHAL:EXCESSIVE INHAL OF VAPS CAN CAUSE NASAL & RESP IRRIT, CNS EFTS INCL DIZZ, WEAK, FATG, NAUS, HDCH, POSS UNCON & EVEN DEATH. INGEST:CAN CAUSE GI IRRIT, NAUS, VOMIT & DIARR. ASPIR(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:OF MATL INTO LUNGS CAN CAUSE CHEM PNEUM WHICH CAN BE FATAL. CHRONIC:MINOR EMBRYOTOX/FETOTOX EFTS HAVE BEEN OBSERVED IN LAB RATS EXPOS TO ING 5 BY INHAL OF LEVELS >1000 PPM (5X PEL) FOR MOST O F GESTATION PERIOD. ING 5 MAY POTENTIATE (SHORTEN TIME OF ONSET) PERIPHERAL NEUROPATHY CAUSED BY METHYL N-BUTYL (ING 8) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:SKIN:THORO WASH EXPOS AREA W/SOAP & WATER. REMOVE & LAUNDER CONTAM CLTHG BEFORE RE-USE. EYES:FLUSH W/LG AMTS OF WATER FOR AT LST 15 MINS, LIFTING UPPER & LOWER LIDS OCCAS, GET MED ATTN. INGEST:DO NOT INDUCE VOMIT, KEEP PERS WARM, QUIET & GET MED ATTN. ASPIR OF MATL INTO LUNGS DUE TO VOMIT CAN CAUSE CHEM PNEUM WHICH CAN BE FATAL. NOTE TO MD:THIS PROD CNTNS METHANOL. METHANOL IS METABOLIZED (ING 16) ===================== Fire Fighting Measures ===================== Flash Point:>10F,>-12C Lower Limits:1.1% Extinguishing Media:REGULAR FOAM, CARBON DIOXIDE OR DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NEVER USE WELDING/CUTTING TORCH ON/NEAR DRUM(EVEN EMPTY) BECAUSE PROD(OR RESIDUE) CAN IGNITE EXPLO. ALL 5 GAL PAILS & LGR METAL CNTNRS INCL TANK CARS/(SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:SM SPILL:ABSORB LIQ ON PAPER, VERMICULITE, FLOOR ABSORB/OTHER ABSORB MATL. LG SPILL:ELIM ALL IGNIT SOURCES(FLARES, FLAMES INCL PILOT LIGHTS, ELEC SPKS). PERS NOT WEARING PROT EQUIP SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN(ING 21) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID &/OR SOLID), ALL HAZARD PRECAUTIONS GIVEN IN THIS MSDS MUST BE OBSERVED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF WORKPLACE EXPOS LIM(S) OF PROD/ANY COMPONENT IS EXCEEDED, NIOSH/MSHA APPRVD AIR SUPPLIED RESP IS ADVISED IN ABSENCE OF PROPER ENVIRON CONTROL. OSHA REGS ALSO PERMIT OTHER NIOSH/MSHA APPRVD RESPS (N EG PRESS TYPE) UNDER SPECIFIED (ING 25) Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL &/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Protective Gloves:RESISTANT GLOVES. Eye Protection:ANSI APPRVD CHEM WORKER GOGGLES . Other Protective Equipment:TO PREVENT REPEATED OR PROLONGED SKIN CONTACT, WEAR IMPERVIOUS CLOTHING & BOOTS. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXPLO HAZ:TRUCKS SHOULD BE GROUNDED &/OR BONDED WHEN MATL IS TRANSFERRED. MATL IS HIGHLY VOLAT & READILY GIVES OFF VAPS WHICH MAY TRAVEL ALONG GROUND/BE MOVED BY VENT & IGNITED BY PILOT LIGHTS, OTHER FLAMES, SPKS, HEATERS, SMOKING, ELEC MOTORS, STATIC DISCHARGE/OTHER IGNIT SOURCES AT LOCATIONS DIST FROM MATL HNDLG PT. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:147F,64C Vapor Pres:97.68 @20C Vapor Density:>1 Spec Gravity:<1 Evaporation Rate & Reference:SLOWER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID CONTACT W/STRONG OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS:CARBON DIOXIDE, CARBON MONOXIDE, VARIOUS HYDROCARBONS, ETC. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF I/A/W ALL APPLICABLE LOCAL, STATE & FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.