QUIKRETE COMPANIES -- QUICK SETTING CEMENT, 1240 -- 5610-00N058946
===================== Product Identification ===================== Product ID:QUICK SETTING CEMENT, 1240 MSDS Date:07/14/1993 FSC:5610 NIIN:00N058946 === Responsible Party === Company Name:QUIKRETE COMPANIES Address:1790 CENTURY CIRCLE City:ATLANTA State:GA ZIP:30345 Country:US Info Phone Num:404-634-9100 Emergency Phone Num:404-634-9100 CAGE:IO174 === Contractor Identification === Company Name:QUIKRETE COMPANIES Address:1790 CENTURY CIRCLE Box:City:ATLANTA State:GA ZIP:30345 Country:US Phone:404-634-9100 CAGE:IO174 ============= Composition/Information on Ingredients ============= Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (SILICA SAND, CRYSTALLINE) CAS:14808-60-7 RTECS #:VV7330000 OSHA PEL:0.1 MG/M3 (MFR) ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:PORTLAND CEMENT CAS:65997-15-1 RTECS #:VV8770000 OSHA PEL:50 MPPCF ACGIH TLV:10 MG/M3 TDUST Ingred Name:CALCIUM (II) SULFATE, DIHYDRATE (1:1:2); (GYPSUM) CAS:10101-41-4 RTECS #:EW4150000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:CALCIUM HYDROXIDE; (LIME) CAS:1305-62-0 RTECS #:EW2800000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:5 MG/M3 Ingred Name:SILICA GEL; (AMORPHOUS SILICA) (FROM FLY ASH OR MICRO SILICA). (MAY CONTAIN ONE OR MORE OF INGS 5 - 9) CAS:112945-52-5 RTECS #:VV7310000 OSHA PEL:6 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:ALUMINUM OXIDE; (ALUMINA (FROM FLY ASH OR CALCIUM ALUMINATE CEMENT)) (SARA 313) CAS:1344-28-1 RTECS #:BD1200000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:CLAY (KAOLIN); (CLAY) CAS:1332-58-7 RTECS #:GF1670500 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:2 MG/M3 TDUST Ingred Name:CALCIUM CARBONATE; (PULVERIZED LIMESTONE) CAS:1317-65-3 RTECS #:EV9580000 OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (GLASS FIBERS) CAS:14808-60-7 RTECS #:VV7330000 OSHA PEL:0.1 MG/M3 (MFR) ACGIH TLV:0.1 MG/M3 RDUST ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE:PROD BECOMES ALKALINE WHEN EXPOS TO MOISTURE. EXPOS CAN DRY SKIN, CAUSE ALKALI BURNS & AFFECT MUC MEMBS. DUST CAN IRRIT EYES & UPPER RESP SYS. TOX EFTS NOTED IN ANIMALS INCL, FOR ACUTE EXPOS, AL VEOLAR DMG W/PULM EDEMA. SIGNS & SYMPS OF EXPOS:SYMPS OF EXCESSIVE EXPOS TO DUST INCL SHORTNESS OF (EFTS OF OVEREXP) Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC MONOGRAPHS, SUPP, VOL 7, PG 341, 1987:GRP 2A. NTP 7TH ANNUAL RPT ON CARCINS, (SUPP DATA) Effects of Overexposure:HLTH HAZ:BREATH & REDUCED PULM FUNCTION. EXCESSIVE EXPOS TO SKIN & EYE ESP WHEN MIXED W/WATER CAN CAUSE CAUSTIC BURNS AS SEV AS THIRD DEGREE. CHRONIC:DUST CAN CAUSE INFLAMM OF LINING TISS OF INTERIOR OF NOSE & INFLAMM OF CORNEA. HYPERSENSITIVE INDIVIDUALS MAY DEVELOP ALLERGIC DERM. EXCESSIVE INHAL OF SILICA (SUPP DATA) Medical Cond Aggravated by Exposure:INDIVIDUALS W/SENSITIVE SKIN & W/PULMONARY &/OR RESPIRATORY DISEASE, INCLUDING, BUT NOT LIMITED TO, ASTHMA & BRONCHITIS, OR SUBJECT TO EYE IRRITATION, SHOULD BE PRECLUDED FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INGEST:CALL MD IMMEDIATELY . EYES:IRRIGATE (FLOOD) IMMEDIATELY & REPEATEDLY W/CLEAN WATER FOR AT LEAST 15 MINUTES. SKIN:WASH EXPOSED AREAS W/SOAP & WATER. IF IRRITATION OR INFLAMMATION OCCURS SE EK PROMPT MEDICAL ATTENTION. INHAL:REMOVE PERSON IMMEDIATELY TO FRESH AIR, GIVE ARTIFICIAL RESPIRATION AS NEEDED. GET PROMPT MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONCOMBUSTIBLE & NOT EXPLOSIVE. ================== Accidental Release Measures ================== Spill Release Procedures:IF SPILLED, USE DUSTLESS METHODS (VACUUM) & PLACE INTO CLOSABLE CONTAINER FOR DISPOSAL OR USE IF NOT CONTAMINATED OR WET. USE ADEQUATE VENTILATION. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:PRECAUTIONS MUST BE OBSERVED BECAUSE BURNS OCCUR W/LITTLE WARNING - LITTLE HEAT IS SENSED. Other Precautions:CUSTOMER-USERS MUST COMPLY W/ALL APPLICABLE HEALTH & SAFETY LAWS, REGULATIONS & ORDERS COVERING SILICA. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IN DUSTY ENVIRONMENTS, THE USE OF A NIOSH/MSHA APPROVED RESPIRATOR IS RECOMMENDED. Ventilation:LOCAL EXHAUST CAN BE USED, IF NECESSARY, TO CONTROL AIRBORNE DUST LEVELS. Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(SUPDAT) Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . USE OF BARRIER CREAMS, BOOTS & CLTHG (SUPDAT) Work Hygienic Practices:FOLLOWING WORK, WORKERS SHOULD SHOWER W/SOAP & WATER. Supplemental Safety and Health MATLS TO AVOID:DIFLUORIDE, MAY CAUSE FIRES. EXPLAN OF CARCIN:1994:ANTIC TO BE CARCIN. EFTS OF OVEREXP:DUST MAY RSLT IN RESP DISEASE, INCL SILICOSIS, PNEUMOCONIOSIS, PULM FIBROSIS & POSSIBLY CANCER. EY E PROT:& FULL LENGTH FACESHIELD .OTHER PROT EQUIP:TO PROTECT SKIN FROM CONTACT IS RECOMMENDED. ================== Physical/Chemical Properties ================== Solubility in Water:SLIGHT Appearance and Odor:GRAY TO BROWN COLORED POWDER W/NO ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONTACT OF SILICA W/POWERFUL OXIDIZING AGENTS SUCH AS FLUORINE, CHLORINE, TRIFLUORIDE, MANGANESE TRIOXIDE, OXYG (SUPDAT) Stability Condition to Avoid:KEEP DRY UNTIL USED TO PRESERVE PRODUCT UTILITY. Hazardous Decomposition Products:SILICA WILL DISSOLVE IN HYDROFLUORIC ACID & PRODUCE A CORROSIVE GAS - SILICON TETRAFLUORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:CAN BE TREATED AS A COMMON WASTE FOR DISPOSAL I/A/W FEDERAL, STATE & LOCAL REGULATIONS. 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